Chiral phonons in binary compounds <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" altimg="si17.svg" display="inline" id="d1e1274"><mml:mi>A</mml:mi></mml:math>Bi (<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" altimg="si17.svg" display="inline" id="d1e1280"><mml:mi>A</mml:mi></mml:math> = K, Rb, Cs) with P2<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" altimg="si12.svg" display="inline" id="d1e1285"><mml:msub><mml:mrow /><mml:mrow><mml:mn>1</mml:mn></mml:mrow></mml…

نویسندگان

چکیده

Binary compounds $A$Bi ($A$ = K, Rb, Cs) crystallize in P2$_1$/c structure containing both clockwise and anticlockwise chiral chains of Bi atoms. Electronic band exhibits the insulating nature these systems, with gap about $0.25$ eV. The presented study dynamical properties confirm a stability system symmetry. crystal contains quasi-one-dimensional chains, exhibiting four-fold-like rotational ``local'' Nevertheless, formally posses two-fold Independently absence three-fold (or higher) symmetry axes for whole crystal, modes propagate along atom systems. We discuss basic monoatomic chains. show that axis affects main phonons, which are not realized at high-symmetry points, but some paths between them reciprocal space. In addition, doped system, phonons possess non-zero total angular momentum.

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ژورنال

عنوان ژورنال: Materials today communications

سال: 2023

ISSN: ['2352-4928']

DOI: https://doi.org/10.1016/j.mtcomm.2023.105888